Whitesides Group - Publications


Publications 1980-1989
273.	"Preparation of Cytidine 5'-Monophospho-N-Acetylneuraminic Acid (CMP-NeuAc) and Uridine 5'-Diphosphoglucuronic Acid (UDP-GlcUA); Syntheses of a-2,6-Sialyllactosamine, a-2,6-Sialyllactose, and Hyaluronic Acid", Simon, E. S., Toone, E. J., Ostroff, G., Bednarski, M. D. and Whitesides, G. M., in Methods Enzymol.: Complex Carbohydrates, Part F, V. Ginsburg, Ed., 1989, 179, 275-287.

272.	"The Synthesis of Aldose Sugars from Half-protected Dialdehydes Using Rabbit Muscle Aldolase", Borysenko, C. W., Spaltenstein, A., Straub, J. A. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 9275-9276.

271.	"Hemagglutinins from Two Influenza Virus Variants Bind to Sialic Acid Derivatives with Millimolar Dissociation Constants: A 500 MHz Proton Nuclear Magnetic Resonance Study", Sauter, N. K., Bednarski, M. D., Wurzburg, B. A., Hanson, J. E., Whitesides, G. M., Skehel, J. J. and Wiley, D. C., Biochemistry, 1989, 28, 8388-8396.

270.	"Lactate Dehydrogenase-Catalyzed Regeneration of NAD from NADH for Use in Enzyme-Catalyzed Synthesis", Chenault, H. K. and Whitesides, G. M., Bioorg. Chem., 1989, 17, 400-409.

269.	"Preparation of Phosphoenolpyruvate from D-(-)-3-Phosphoglyceric Acid for Use in Regeneration of ATP", Simon, E. S., Grabowski, S. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 8920-8921.

268.	"Enzyme-Catalyzed Synthesis of Carbohydrates", Toone, E. J., Simon, E. S., Bednarski, M. D. and Whitesides, G. M., Tet. Rep., 1989, 45, 5365-5422.

267.	"The Physical-Organic Chemistry of Surfaces, and Its Relevance to Molecular Recognition", Whitesides, G. M. and Biebuyck, H., in Molecular Recognition: Chemical and Biochemical Problems, S. M. Roberts, Ed., Royal Society of Chemistry, Cambridge, 1989, 78, 270-285.

266.	"A New, General Method for the Determination of Binding Constants: Photoacoustic Titration of Dansylamide with Carbonic Anhydrase", Jain, A., Marzluff, E. M., Jacobsen, J. R., Whitesides, G. M. and Grabowski, J. J., J. Chem. Soc. Chem. Comm., 1989, 1557-1559.

265.	"Orthogonal Systems for Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic Acids on Alumina", Laibinis, P. E., Hickman, J. J., Wrighton, M. S. and Whitesides, G. M., Science, 1989, 245, 845-847.

264.	"Combining Spontaneous Molecular Assembly with Microfabrication to Pattern Surfaces: Selective Binding of Isonitrile to Platinum Microwires and Characterization by Electrochemistry and Surface Spectroscopy", Hickman, J. J., Zou, C., Ofer, D., Harvey, P., Wrighton, M. S., Laibinis, P. E., Bain, C. D. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 7271-7272.

263.	"Synthesis without Cells", Simon, E. S., Akiyama, A. and Whitesides, G. M., in A Revolution in Biotechnology, J. L. Marx, Ed., ICSU Press, Cambridge, 1989, 15-27.

262.	"Modelling Organic Surfaces with Self-Assembled Monolayers", Bain, C. D. and Whitesides, G. M., Angew. Chem. Int. Ed. Engl., 1989, 28, 506-516.

261.	"The Mechanism of Formation of Grignard Reagents: Trapping of Free Alkyl Radical Intermediates by Reaction with Tetramethylpiperidine-N-oxyl", Root, K. S., Hill, C. L., Lawrence, L. M. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 5405-5412.

260.	"A Study by Contact Angle of the Acid-Base Behavior of Monolayers Containing w-Mercaptocarboxylic Acids Adsorbed on Gold: An Example of Reactive Spreading", Bain, C. D. and Whitesides, G. M., Langmuir, 1989, 5, 1370-1378.

259.	"Formation of Monolayers by the Coadsorption of Thiols on Gold: Variation in the Length of the Alkyl Chain", Bain, C. D. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 7164-7175.

258.	"Formation of Monolayers by the Coadsorption of Thiols on Gold: Variation in the Head Group, Tail Group, and Solvent", Bain, C. D., Evall, J. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 7155-7164.

257.	"Kinetic Resolution of Unnatural and Rarely Occurring Amino Acids: Enantioselective Hydrolysis of N-Acyl Amino Acids Catalyzed by Acylase I", Chenault, H. K., Dahmer, J. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 6354-6364.

256.	"D-Lactate Dehydrogenase: Substrate Specificity and Use as a Catalyst in the Synthesis of Homochiral 2-Hydroxy Acids", Simon, E. S., Plante, R. and Whitesides, G. M., Appl. Biochem. Biotech., 1989, 22, 169-179.

255.	"Structure and Reactivity of Alkylsiloxane Monolayers Formed by Reaction of Alkyltrichlorosilanes on Silicon Substrates", Wasserman, S. R., Tao, Y.-T. and Whitesides, G. M., Langmuir, 1989, 5, 1074-1087.

254.	"Monolayers of 11-Trichlorosilylundecyl Thioacetate: A System that Promotes Adhesion between Silicon Dioxide and Evaporated Gold", Wasserman, S. R., Biebuyck, H. and Whitesides, G. M., J. Mater. Res., 1989, 4, 886-891.

253.	"The Structure of Self-Assembled Monolayers of Alkylsiloxanes on Silicon: A Comparison of Results from Ellipsometry and Low-Angle X-Ray Reflectivity", Wasserman, S. R., Whitesides, G. M., Tidswell, I. M., Ocko, B. M., Pershan, P. S. and Axe, J. D., J. Am. Chem. Soc., 1989, 111, 5852-5861.

252.	"Comparison of Self-Assembled Monolayers on Gold: Coadsorption of Thiols and Disulfides", Bain, C. D., Biebuyck, H. A. and Whitesides, G. M., Langmuir, 1989, 5, 723-727.

251.	"Attenuation Lengths of Photoelectrons in Hydrocarbon Films", Bain, C. D. and Whitesides, G. M., J. Phys. Chem., 1989, 93, 1670-1673.

250.	"Characterization and Stability of Cyclic Disulfides and Cyclic Dimeric Bis(disulfides)", Houk, J. and Whitesides, G. M., Tetrahedron, 1989, 45, 91-102.

249.	"Rabbit Muscle Aldolase (RAMA) as a Catalyst in Organic Synthesis", Bednarski, M. D., Simon, E. S., Bischofberger, N., Fessner, W.-D., Kim, M.-J., Lees, W., Saito, T., Waldmann, H. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 627-635.

248.	"Enzymatic Baeyer-Villiger Type Oxidations of Ketones Catalyzed by Cyclohexanone Oxygenase", Abril, O., Ryerson, C. C., Walsh, C. and Whitesides, G. M., Bioorg. Chem., 1989, 17, 41-52.

247.	"Oxidation of 2-Propanol to Acetone by Dioxygen on a Platinized Electrode under Open-Circuit Conditions", DiCosimo, R. and Whitesides, G. M., J. Phys. Chem., 1989, 93, 768-775.

246.	"Liquid-Phase Oxidation of 2-Propanol to Acetone by Dioxygen Using Supported Platinum Catalysts", Nicoletti, J. W. and Whitesides, G. M., J. Phys. Chem., 1989, 93, 759-767.

245.	"A Combined Chemical-Enzymatic Synthesis of 3-Deoxy-D-arabino-heptulosonic Acid 7-Phosphate", Turner, N. J. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 624-627.

244.	"Enzymatic Methods for the Preparation of Acetyl-CoA and Analogs", Billhardt, U.-M., Stein, P. and Whitesides, G. M., Bioorg. Chem., 1989, 17, 1-12.

243.	"Formation of Monolayer Films by the Spontaneous Assembly of Organic Thiols from Solution onto Gold", Bain, C. D., Troughton, E. B., Tao, Y.-T., Evall, J., Whitesides, G. M. and Nuzzo, R. G., J. Am. Chem. Soc., 1989, 111, 321-335.

242.	"The Anthranilate Amide of 'Polyethylene Carboxylic Acid' Shows an Exceptionally Large Change with pH in Its Wettability by Water", Wilson, M. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 8718-8719.

241.	"Poly(3-n-butyl-2,5-diethynylenethiophenylene): A Soluble Polymer Containing Diacetylene Units and Its Conversion to a Highly-Cross-Linked Organic Solid", Callstrom, M. R., Neenan, T. X. and Whitesides, G. M., Macromolecules, 1988, 21, 3528-3530.

240.	"Hyper-Cross-Linked Organic Solids: Preparation from Poly(aryldiacetylenes) and Preliminary Measurements of their Young's Modulus, Hardness and Thermal Stability", Neenan, T. X., Callstrom, M. R., Scarmoutzos, L. M., Stewart, K. R. and Whitesides, G. M., Macromolecules, 1988, 21, 3525-3528.

239.	"Formation of Two-Component Surfaces by the Spontaneous Assembly of Monolayers on Gold from Solutions Containing Mixtures of Organic Thiols", Bain, C. D. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 6560-6561.

238.	"Materials for Advanced Electronic Devices", Whitesides, G. M., in Biotechnology and Materials Science: Chemistry for the Future, M. A. Good, Ed., American Chemical Society, Washington, 1988, 85-99.

237.	"Depth Sensitivity of Wetting: Monolayers of w-Mercaptoethers on Gold", Bain, C. D. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 5897-5898.

236.	"Organic Chemistry in Two Dimensions: Surface-Functionalized Polymers and Self-Assembled Monolayer Films", Whitesides, G. M. and Ferguson, G. S., Chemtracts, 1988, 1, 171-187.

235.	"Cofactor Regeneration for Enzyme-Catalyzed Synthesis", Chenault, H. K., Simon, E. S. and Whitesides, G. M., in Biotechnology & Genetic Engineering Reviews, G. E. Russell, Ed., Intercept, Wimborne, 1988, 6, 221-270.

234.	"Correlation between Wettability and Structure in Monolayers in Alkanethiols Adsorbed on Gold", Bain, C. D. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 3665-3666.

233.	"Synthesis of CMP-NeuAc from N-Acetylglucosamine: Generation of CTP from CMP using Adenylate Kinase", Simon, E. S., Bednarski, M. D. and Whitesides, G. M., J. Am. Chem. Soc. , 1988, 110, 7159-7163.

232.	"Synthesis of Analogs of 1,3-Dihydroxyacetone Phosphate and Glyceraldehyde-3-phosphate for Use in Studies of Fructose-1,6-Diphosphate Aldolase", Bischofberger, N., Waldmann, H., Saito, T., Simon, E. S., Lees, W., Bednarski, M. D. and Whitesides, G. M., Journal of Organic Chemistry, 1988, 53, 3457-3465.

231.	"Intermolecular Activation of C-D Bonds in Benzene-d6 by trans-Neopentyl(trifluoromethanesulfonato)bis(trimethylphosphine)platinum(II)", Brainard, R. L., Nutt, W. R., Lee, T. R. and Whitesides, G. M., Organometallics, 1988, 7, 2379-2386.

230.	"Enzymes as Catalysts in Organic Synthesis", Akiyama, A., Bednarski, M., Kim, M.-J., Simon, E. S., Waldmann, H. and Whitesides, G. M., Chemtech, 1988, 627-634.

229.	"Molecular-Level Control over Surface Order in Self-Assembled Monolayer Films of Thiols on Gold", Bain, C. D. and Whitesides, G. M., Science, 1988, 240, 62-63.

228.	"The Synthesis of High Carbon Materials from Acetylenic Precursors. Preparation of Aromatic Monomers Bearing Multiple Ethynyl Groups", Neenan, T. X. and Whitesides, G. M., J. Org. Chem., 1988, 53, 2489-2496.

227.	"L-Lactate Dehydrogenase: Substrate Specificity and Use as a Catalyst in the Synthesis of Homochiral 2-Hydroxy Acids", Kim, M.-J. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 2959-2964.

226.	"Wetting of Functionalized Polyethylene Film Having Ionizable Organic Acids and Bases at the Polymer-Water Interface: Relations between Functional Group Polarity, Extent of Ionization, and Contact Angle with Water", Holmes-Farley, S. R., Bain, C. and Whitesides, G. M., Langmuir, 1988, 4, 921-937.

225.	"Isotopic Exchange Reactions Occurring in the Hydrogenation of 1,5-Cyclooctadienedialkylplatinum(II) Complexes over Platinum Black", Miller, T. M. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 3164-3170.

224.	"Deuterium Labeling Experiments Relevant to the Mechanism of Platinum-Catalyzed Hydrogenation of Diolefindialkylplatinum(II) Complexes: Evidence for Isotopic Exchange via Platinum Surface Hydrogen; the Stereochemistry of Reduction", Miller, T. M., McCarthy, T. J. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 3156-3163.

223.	"Heterogeneous, Platinum-Catalyzed Hydrogenation of Diolefindialkylplatinum(II) Complexes: Kinetics", Miller, T. M., Izumi, A. N., Shih, Y.-S. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 3146-3156.

222.	"The Structures of Self-Assembled Monolayer Films of Organosulfur Compounds Adsorbed on Gold Single Crystals: Electron Diffraction Studies", Strong, L. and Whitesides, G. M., Langmuir, 1988, 4, 546-558.

221.	"Monolayer Films Prepared by the Spontaneous Self-Assembly of Symmetrical and Unsymmetrical Dialkyl Sulfides from Solution onto Gold Substrates: Structure, Properties, and Reactivity of Constituent Functional Groups", Troughton, E. B., Bain, C. D., Whitesides, G. M., Nuzzo, R. G., Allara, D. L. and Porter, M. D., Langmuir, 1988, 4, 365-385.

220.	"The Use of Enzymes as Catalysts for Synthesis in Medicinal Chemistry: Chiral Synthons and Carbohydrates", Whitesides, G. M. and Kim, M.-J., in New Methods in Drug Research, Vol. 2, A. Makriyannis, Ed., J.R. Prous, Philadelphia, 1988, 1-15.

219.	"[Bis(dicyclohexylphosphino)ethane]platinum(0): Reactions with Alkyl, (Trimethylsilyl)methyl, Aryl, Benzyl, and Alkynyl Carbon-Hydrogen Bonds", Hackett, M. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 1449-1462.

218.	"The Activation of the C-H Bonds of Benzene by Reaction with [Bis(dicyclo-hexylphosphino)ethane]platinum(0), Generated by the Thermolysis of cis-[Bis(dicyclohexylphosphino)ethane](hydride)(neopentyl)platinum(II)", Hackett, M., Ibers, J. A. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 1436-1448.

217.	"Generation of Cytidine 5'-Triphosphate Using Adenylate Kinase", Simon, E. S., Bednarski, M. D. and Whitesides, G. M., Tet. Lett., 1988, 29, 1123-1126.

216.	"Synthesis of 3-Deoxy-D-manno-2-octulosonate-8-phosphate (KDO-8-P) from D-Arabinose: Generation of D-Arabinose-5-Phosphate Using Hexokinase", Bednarski, M. D., Crans, D. C., DiCosimo, R., Simon, E. S., Stein, P. D. and Whitesides, G. M., Tet. Lett., 1988, 29, 427-430.

215.	"Carlons: Organic Polymers from Condensation of Carbon Dinucleophiles with Difunctional Derivatives of Carboxylic Acids", Kool, L. B. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 306-307.

214.	"Enzyme-Catalyzed Synthesis of Nucleoside Triphosphates from Nucleoside Monophosphates: ATP from AMP and Ribavirin 5'-triphosphate from Ribavirin 5'-monophosphate", Kim, M.-J. and Whitesides, G. M., Appl. Biochem. Biotech., 1987, 16, 95-108.

213.	"Enzymatic Regeneration of Adenosine 5'-Triphosphate: Acetyl Phosphate, Phosphoenylpyruvate, Methoxycarbonyl Phosphate, Dihydroxyacetone Phosphate, 5-Phospho-a-D-ribosyl Pyrophosphate, Uridine-5'-diphosphoglucose", Crans, D. C., Kazlauskas, R. J., Hirschbein, B. L., Wong, C.-H., Abril, O. and Whitesides, G. M., in Methods Enzymol.: Immobilized Enzymes/Cells, Pt. C, K. Mosbach, Ed., 1987, 136, 263-80.

212.	"Protein Synthesis in Cell-Free Reticulocyte Lysates on Multi-Hour Incubation", Findeis, M. A. and Whitesides, G. M., Appl. Biochem. Biotech., 1987, 15, 169-189.

211.	"Placeholder-No publication with this call number",,, 1987.,, 1987.

210.	"The Measurement of Thiol-Disulfide Interchange Reactions and Thiol pKa Values", Houk, J., Singh, R. and Whitesides, G. M., in Methods in Enzymology: Sulfur and Sulfur Amino Acids, W. B. Jakoby and O. W. Griffith, Eds., Academic Press, New York, 1987, 129-143.

209.	"Structure-Reactivity Relations for Thiol-Disulfide Interchange", Houk, J. and Whitesides, G. M., J. Am. Chem. Soc., 1987, 109, 6825-6836.

208.	"What, If Anything, Can Chemistry Offer to Fracture Mechanics?", G. M. and Neenan, T. X., in Chemistry and Physics of Fracture, NATO ASI Series E: Applied Sciences - No. 130, R. M. Latanision, Ed., Dordrecht, 1987, 12-22.

207.	"Enzymes in Organic Synthesis", Waldmann, H. and Whitesides, G. M., in Ullmann's Encyclopedia of Industrial Chemistry, A9:

206.	"Limited Nerve Impulse Blockade by 'Leashed' Local Anesthetics", Butterworth, J. F., Moran, J. R., Whitesides, G. M. and Strichartz, G. R., J. Med. Chem., 1987, 30, 1295-1302.

205.	"A Short Synthesis of Ambrox� from Sclareol", Decorzant, R., Vial, C., N�f, F. and Whitesides, G. M., Tetrahedron, 1987, 43, 1871-1879.

204.	"Enzymes as Catalysts in Practical Organic Synthesis", Akiyama, A., Bednarski, M., Kim, M.-J. S., E.S., Waldmann, H. and Whitesides, G. M., Chem. Britain, 1987, 23, 645-654.

203.	"The Enantiomeric Purity of Polar Substrates Can Be Determined with Chiral Lanthanide NMR Shift Reagents in Polar Solvents", Sweeting, L. M., Crans, D. C. and Whitesides, G. M., J. Org. Chem., 1987, 52, 2273-2276.

202.	"Fumarase-Catalyzed Synthesis of L-threo-Chloromalic Acid, and Its Conversion to 2-Deoxy-D-Ribose and D-erythro-Sphingosine", Findeis, M. A. and Whitesides, G. M., J. Org. Chem., 1987, 52, 2838-2848.

201.	"Regeneration of Nicotinamide Cofactors for Use in Enzymatic Synthesis", Chenault, K. and Whitesides, G. M., Appl. Biochem. Biotech., 1987, 14, 147-197.

200.	"Enzymatic Routes to Enantiomerically Enriched 1-Butene Oxide", Chenault, H. K., Kim, M.-J., Akiyama, A., Miyazawa, T., Simon, E. and Whitesides, G. M., J. Org. Chem., 1987, 52, 2608-2611.

199.	"Membrane-Enclosed Enzymatic Catalysis (MEEC): A Useful, Practical Method for the Manipulation of Enzymes in Organic Synthesis", Bednarski, M. D., Chenault, H. K., Simon, E. S. and Whitesides, G. M., J. Am. Chem. Soc., 1987, 109, 1283-1285.

198.	"Reconstruction of the Interface of Oxidatively Functionalized Polyethylene (PE-CO2H) and Derivatives on Heating", Holmes-Farley, S. R., Reamey, R. H., Nuzzo, R., McCarthy, T. J. and Whitesides, G. M., Langmuir, 1987, 3, 799-815.

197.	"The Synthesis and Thermolysis of Dimethylbis(trialkylphosphine)-platinum(II) Complexes in Which the Phosphine Ligands Contain Adamantyl, Adamantylmethyl, and Methyl Groups", Hackett, M. and Whitesides, G. M., Organometallics, 1987, 6, 403-410.

196.	"The Enzymatic Utilization of Sucrose in the Synthesis of Amylose and Derivatives of Amylose Using Phosphorylases", Waldmann, H., Gygax, D., Bednarski, M., Shangraw, W. R. and Whitesides, G. M., Carbohyd. Res., 1986, 157, c4-c7.

195.	"The Reactivity of Carboxylic Acid and Ester Groups in the Functionalized Interfacial Region of 'Polyethylene Carboxylic Acid' (PE-CO2H) and Derivatives: Differentiation of the Functional Groups into Shallow and Deep Subsets Based on a Comparison of Contact Angle and ATR-IR Measurements", Holmes-Farley, S. R. and Whitesides, G. M., Langmuir, 1986, 2, 62-76.

194.	"Cis[bis(dicyclohexylphosphino)ethane]platinum(0) Reacts with Unactivated Carbon-Hydrogen Bonds", Hackett, M., Ibers, J. A., Jernakoff, P. and Whitesides, G. M., J. Am. Chem. Soc., 1986, 108, 8094-8095.

193.	"Aldolase-Catalyzed Synthesis of Complex C8 and C9 Monosaccharides", Bednarski, M. D., Waldmann, H. J. and Whitesides, G. M., Tet. Lett., 1986, 5807-5810.

192.	"Synthesis of a Water-Soluble Derivative of Cyclohexatriacontane-1,2,13,14,25,26-hexone", Mandeville, W. H. and Whitesides, G. M., J. Org. Chem., 1986, 51, 3257-3261.

191.	"Radical Isomerization during Grignard Reagent Formation. A Quantitative Treatment", Garst, J. F., Deutch, J. E. and Whitesides, G. M., J. Am. Chem. Soc., 1986, 108, 2490-2491.

190.	"Chemistry and Materials Science: Molecular Design and Engineering", Whitesides, G. M., Wrighton, M. S. and Parshall, G., in Advancing Materials Research, National Academy of Sciences, Washington, D.C., 1986, 203-224.

189.	"Improved Adhesion of Thin Conformal Organic Films to Metal Surfaces", Stewart, K. R., Whitesides, G. M., Godfried, H. P. and Silvera, I. F., Rev. Sci. Instrum., 1986, 57, 1381-1383.

188.	"The Mechanisms of Thermal Decomposition of trans-Chloroneopentylbis(tricyclopentylphosphine)platinum(II)", Brainard, R. L., Miller, T. M. and Whitesides, G. M., Organometallics, 1986, 5, 1481-1490.

187.	"Fluorescence Properties of Dansyl Groups Covalently Bonded to the Surface of Oxidatively Functionalized Low-Density Polyethylene Film", Holmes-Farley, S. R. and Whitesides, G. M., Langmuir, 1986, 2, 266-282.

186.	"The Mechanism of Thermal Decomposition of Bis(tricyclopentylphosphine)-platinacyclopentane(II): Intramolecular b-Hydride Elimination from the Platinacyclopentane Ring is Slow Relative to an Intermolecular Chain Reaction Involving Hydridoplatinum Intermediates", Miller, T. M. and Whitesides, G. M., Organometallics, 1986, 5, 1473-1480.

185.	"Preparation of Optically Active 1,2-Diols and a-Hydroxyketones Using Glycerol Dehydrogenase as Catalyst: Limits to Enzyme-Catalyzed Synthesis Due to Non-competitive and Mixed Inhibition by Product", Lee, L. G. and Whitesides, G. M., J. Org. Chem., 1986, 51, 25-36.

184.	"Acid-Based Behavior of Carboxylic Acid Groups Covalently Attached at the Surface of Polyethylene: The Usefulness of Contact Angle in Following the Ionization of Surface Functionality", Holmes-Farley, S. R., Reamey, R. H., McCarthy, T. J., Deutch, J. and Whitesides, G. M., Langmuir, 1985, 1, 725-740.

183.	"Glycerol Kinase: Synthesis of Dihydroxyacetone Phosphate, sn-Glycerol-3-Phosphate, and Chiral Analogues", Crans, D. C. and Whitesides, G. M., J. Am. Chem. Soc., 1985, 107, 7019-7027.

182.	"Glycerol Kinase: Substrate Specificity", Crans, D. C. and Whitesides, G. M., J. Am. Chem. Soc., 1985, 107, 7008-7018.

181.	"Enzymes as Catalysts in Synthetic Organic Chemistry", Whitesides, G. M. and Wong, C.-H., Angew. Chem. Int. Ed. Engl., 1985, 24, 617-638.

180.	"Enzyme-Catalyzed Organic Synthesis: A Comparison of Strategies for in situ Regeneration of NAD from NADH", Lee, L. G. and Whitesides, G. M., J. Am. Chem. Soc., 1985, 107, 6999-7008.

179.	"Suppression of Unwanted Heterogeneous Platinum(0)-Catalyzed Reactions by Poisoning with Mercury(0) in Systems Involving Competing Homogeneous Reactions of Soluble Organoplatinum Compounds: Thermal Decomposition of Bis(triethylphosphine)-3,3,4,4-tetramethylplatinacyclopentane", Whitesides, G. M., Hackett, M., Brainard, R. L., Lavalleye, J.-P. P. M., Sowinski, A. F., Izumi, A. N., Moore, S. S., Brown, D. W. and Staudt, E. M., Organometallics, 1985, 4, 1819-1830.

178.	"The Mechanism of Thermal Decomposition of trans-Chloroethylbis-(triethylphosphine)platinum(II)", Brainard, R. L. and Whitesides, G. M., Organometallics, 1985, 4, 1550-1557.

177.	"Enzymatic Synthesis of DeoxyATP Using DNA as Starting Material", Ladner, W. E. and Whitesides, G. M., J. Org. Chem., 1985, 50, 1076-1079.

176.	"Organic Synthesis Using Enzymes", Whitesides, G. M., in Organic Chemical Synthesis Using Enzymes, Ciba Foundation Symposium No. 111, Ciba Foundation, London, 1985, 76-90.

175.	"Synthesis of Methoxycarbonyl Phosphate, A New Reagent Having High Phosphoryl Donor Potential for Use in ATP Cofactor Regeneration", Kazlauskas, R. J. and Whitesides, G. M., J. Org. Chem., 1985, 50, 1069-1076.

174.	"Organic Chemicals from Marine Sources", Whitesides, G. M. and Elliot, J., in Biotechnology in the Marine Sciences, R. M. Colwell, E. R. Pariser and A. J. Sinskey, Eds., John Wiley, New York, 1984, 135-152.

173.	"Lipase-Catalyzed Hydrolysis as a Route to Esters of Chiral Epoxy Alcohols", Ladner, W. E. and Whitesides, G. M., J. Am. Chem. Soc., 1984, 106, 7250-7251.

172.	"Enzymatic Methods in Organic Synthesis", Findeis, M. A. and Whitesides, G. M., Ann. Rep. Med. Chem., 1984, 19, 263-272.

171.	"Enzymatic Synthesis of Arginine Phosphate with Coupled ATP Cofactor Regeneration", Bolte, J. and Whitesides, G. M., Bioorg. Chem., 1984, 12, 170-175.

170.	"A Practical Enzymatic Synthesis of (SP)-Adenosine 5'-O-(1-Thiotriphosphate)((SP)-ATP-a-S)", Moran, J. R. and Whitesides, G. M., J. Org. Chem., 1984, 49, 704-706.

169.	"Practical Enzymatic Synthesis of Adenosine-5'-O-(3-Thiophosphate)(ATP-g-S)", Abril, O., Crans, D. C. and Whitesides, G. M., J. Org. Chem., 1984, 49, 1360-1364.

168.	"An Efficient Chemical and Enzymatic Synthesis of Nicotinamide Adenine Dinucleotide (NAD+)", Walt, D. R., Rios-Mercadillo, V. M., Aug�, J. and Whitesides, G. M., J. Am. Chem. Soc., 1984, 106, 234-239.

167.	"The Mechanism of Hydrogenolysis of Dineopentylbis(triethylphosphine)platinum(II)", Reamey, R. H. and Whitesides, G. M., J. Am. Chem. Soc., 1984, 106, 81-85.

166.	"Organometallic Reactions of Platinum Involving Metallic Hydrides", Whitesides, G. M., Reamey, R. H., Brainard, R. L., Izumi, A. N. and McCarthy, T. J., Annals New York Acad. Sci., 1983, 415, 56-66.

165.	"Chemical Modification of Acrylamide Gels: Verification of the Role of Ionization in Phase Transitions", Nicoli, D., Young, C., Tanaka, T., Pollak, A. and Whitesides, G. M., Macromolecules, 1983, 16, 887-890.

164.	"Magnetic Separations in Biotechnology", Whitesides, G. M., Kazlauskas, R. and Josephson, L., TIBTECH, 1983, 1, 144-148.

163.	"Practical Synthesis of 5-Phospho-D-ribosyl-a-1-pyrophosphate (PRPP): Enzymatic Routes from Ribose-5-phosphate or Ribose", Gross, A., Abril, O., Lewis, J. M., Geresh, S. and Whitesides, G. M., J. Am. Chem. Soc., 1983, 105, 7428-7434.

162.	"Enzymes as Catalysts in Organic Synthesis", Whitesides, G. M. and Wong, C.-H., Aldrichimica Acta, 1983, 16, 27-34.

161.	"A Convenient Synthesis of Disodium Acetyl Phosphate for Use in situ ATP Cofactor Regeneration", Crans, D. C. and Whitesides, G. M., J. Org. Chem., 1983, 26, 3130-3132.

160.	"Enzymatic Synthesis of S-Adenosyl-L-Methionine from L-Methionine and ATP", Gross, A., Geresh, S. and Whitesides, G. M., Appl. Biochem. Biotech., 1983, 8, 415-422.

159.	"Enzyme-Catalyzed Organic Synthesis: Regeneration of Deuterated Nicotinamide Cofactors for Use in Large-Scale Enzymatic Synthesis of Deuterated Substances", Wong, C.-H. and Whitesides, G. M., J. Am. Chem. Soc., 1983, 105, 5012-5014.

158.	"Synthesis of Sugars by Aldolase-Catalyzed Condensation Reactions", Wong, C.-H. and Whitesides, G. M., J. Org. Chem., 1983, 48, 3199-3205.

157.	"Chemical and Enzymatic Synthesis of 6-Deoxyhexoses. Conversion to 2,5-Dimethyl-4-Hydroxy-2,3-Dihydro-furan-3-one (Furaneol�) and Analogues", Wong, C.-H. and Whitesides, G. M., J. Org. Chem., 1983, 48, 3493-3497.

156.	"Activation Parameters for Thiolate-Disulfide Interchange", Whitesides, G. M., Houk, J. and Patterson, M. A. K., J. Org. Chem., 1983, 48, 112-115.

155.	"Relations between Fracture and Coordination Chemistry", Whitesides, G. M., in Atomistics of Fracture, R. M. Latanision and J. R. Pickens, Eds., Plenum Press, New York, 1983, 337-362.

154.	"Preparation of a Mixture of Nucleoside Triphosphates from Yeast RNA: Use in Enzymatic Synthesis Requiring Nucleoside Triphosphate Regeneration, and Conversion to Nucleoside Diphosphate Sugars", Wong, C.-H., Haynie, S. L. and Whitesides, G. M., J. Am. Chem. Soc., 1983, 105, 115-117.

153.	"Enzyme-Catalyzed Synthesis of N-Acetyllactosamine with in situ Regeneration of Uridine 5'-Diphosphate Glucose and Uridine 5'-Diphosphate Galactose", Wong, C.-H., Haynie, S. L. and Whitesides, G. M., J. Org. Chem., 1982, 47, 5416-5418.

152.	"Ribulose-1,5-Biphosphate: Routes from Glucose-6-Phosphate (via 6-Phosphogluconate and Ribulose-5-phosphate) and from Adenosine Monophosphate (via Ribose-5-phosphate and Ribulose-5-phosphate)", Wong, C.-H., Pollak, A., McCurry, S. D., Sue, M. M., Knowles, J. R. and Whitesides, G. M., in Methods in Enzymology, W. A. Wood, Ed., Academic Press, New York, 1982, 108-121.

151.	"Asymmetric Synthesis Using Cofactor-Requiring Enzymes", Whitesides, G. M., Wong, C.-H. and Pollak, A., in Asymmetric Reactions and Processes in Chemistry, E. Eliel and S. Otsuka, Eds., American Chemical Society, Washington, D.C., 1982, 185, 1-205.

150.	"Synthesis of Phosphoenolpyruvate and Its Use in ATP Cofactor Regeneration", Hirschbein, B. L., Mazenod, F. P. and Whitesides, G. M., J. Org. Chem., 1982, 47, 3765-3766.

149.	"Enzyme-Catalyzed Transhydrogenation between Nicotinamide Cofactors and Its Application in Organic Synthesis", Wong, C.-H. and Whitesides, G. M., J. Am. Chem. Soc., 1982, 104, 3542-3544.

148.	"Enzyme-Catalyzed Organic Synthesis: NAD(P)H Cofactor Regeneration Using Ethanol/Alcohol Dehydrogenase/Aldehyde Dehydrogenase and Methanol/Alcohol Dehydrogenase/Aldehyde Dehydrogenase/Formate Dehydrogenase", Wong, C.-H. and Whitesides, G. M., J. Org. Chem., 1982, 47, 2816-2818.

147.	"Laboratory-Scale Enzymatic/Chemical Synthesis of D- and L-b-Chlorolactic Acid and D- and L-Potassium Glycidate", Hirschbein, B. L. and Whitesides, G. M., J. Am. Chem. Soc., 1982, 104, 4458-4460.

146.	"Reductive Elimination of a Carbon-Carbon Bond from Bis(trialkylphosphine)-3,3-dimethylplatinacyclopropane Produces Bis(trialkylphosphine)-platinum(0) and 1,1-Dimethylcyclopropane", DiCosimo, R. and Whitesides, G. M., J. Am. Chem. Soc., 1982, 104, 3601-3607.

145.	"Synthesis and Coordinating Properties of Heterocyclic Tertiary Phosphines", Moore, S. S. and Whitesides, G. M., J. Org. Chem., 1982, 47, 1489-1493.

144.	"Magnetic Separations in Chemistry and Biochemistry", Hirschbein, B. L., Brown, D. W. and Whitesides, G. M., Chemtech., 1982, 12, 172-179.

143.	"Reductive Elimination of H-H, H-CH3, and CH3-CH3 from Bis(phosphine)-platinum(II), -palladium(II), and -nickel(II) Complexes: A Theoretical Study Using the SCF-Xa-SW Method", Balazs, A. C., Johnson, K. H. and Whitesides, G. M., Inorg. Chem., 1982, 21, 2162-2174.

142.	"Structures of Dineopentylbis(triethylphosphine)platinum(II) and Bis(triethylphosphine)-3,3-dimethylplatinacyclobutane: Reactant and Product in a Thermal Cyclometallation Reaction", Ibers, J. C., DiCosimo, R. and Whitesides, G. M., Organometallics, 1982, 1, 13-20.

141.	"Affinity Separation of Enzymes from Mixtures Containing Suspended Solids: Comparisons of Magnetic and Non-Magnetic Techniques", Hirschbein, B. L. and Whitesides, G. M., Appl. Biochem. Biotech., 1982, 7, 157-176.

140.	"Hybrid Organometallic/Enzymatic Catalyst Systems: Regeneration of NADH Using Dihydrogen", Abril, O. and Whitesides, G. M., J. Am. Chem. Soc., 1982, 104, 1552-1554.

139.	"Cyclometalation of Dialkylbis(triethylphosphine)platinum(II) Complexes: Formation of Pt, Pt-Bis(triethylphosphine)platinacycloalkanes", DiCosimo, R., Moore, S. S., Sowinski, A. F. and Whitesides, G. M., J. Am. Chem. Soc., 1982, 104, 124-133.

138.	"Enzymatic Conversion of a-Ketoaldehydes to Optically Active a-Hydroxacids Using Glyoxalase I and II", Patterson, M. A. K., Szajewski, R. P. and Whitesides, G. M., J. Org. Chem., 1981, 46, 4682-4685.

137.	"Regeneration of NAD(P)H Using Glucose-6-Sulfate and Glucose-6-Phosphate Dehydrogenase", Wong, C.-H., Gordon, J., Cooney, C. L. and Whitesides, G. M., J. Org. Chem., 1981, 46, 4676-4679.

136.	"Enzyme-Catalyzed Organic Synthesis: Electrochemical Regeneration of NAD(P)H from NAD(P) Using Methyl Viologen and Flavoenzymes", DiCosimo, R., Wong, C.-H., Daniels, L. and Whitesides, G. M., J. Org. Chem., 1981, 46, 4622-4623.

135.	"A Combined Electrochemical/Enzymatic Method for in situ Regeneration of NADH Based on Cathodic Reduction of Cyclic Disulfides", Shaked, Z., Barber, J. J. and Whitesides, G. M., J. Org. Chem., 1981, 46, 4100-4101.

134.	"Enzyme-Catalyzed Organic Synthesis: NAD(P)H Regeneration Using Dihydrogen and the Hydrogenase from Methanobacter thermoautotrophicum", Wong, C.-H., Daniels, L., Orme-Johnson, W. H. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 6227-6228.

133.	"Synthesis of Functional Chelating Diphosphines Containing the Bis[2-(diphenylphosphino)ethyl]amino Moiety and the Use of These Materials in the Preparation of Water-Soluble Diphosphine Complexes of Transition Metals", Nuzzo, R. G., Haynie, S. L., Wilson, M. E. and Whitesides, G. M., J. Org. Chem., 1981, 46, 2861-2867.

132.	"The Mechanism of Formation of Grignard Reagents. The Rate of Reaction of Cyclopentyl Bromide with a Rotating Magnesium Disk", Root, K. S., Deutch, J. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 5475-5479.

131.	"Heterogenous Platinum-Catalyzed Hydrogenation of Dialkyl(diolefin)platinum(II) Complexes", McCarthy, T. J., Shih, Y.-S. and Whitesides, G. M., Proc. Nat. Acad. Sci. USA, 1981, 78, 4649-4651.

130.	"The Mechanisms of Thermal Decomposition of Dialkylbis(triethylphosphine)platinum(II) Complexes", Whitesides, G. M., Pure Appl. Chem., 1981, 53, 287-292.

129.	"Enzyme-Catalyzed Organic Synthesis: NAD(P)H Cofactor Regeneration Using Glucose-6-Phosphate and the Glucose-6-Phosphate Dehydrogenase from Leuconostoc mesenteroides", Wong, C.-H. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 4890-4899.

128.	"Apparent Fluxionality in Diethyl(phosphine)platinum(II), a Coordinately Unsaturated Intermediate in b-Hydride Elimination", McCarthy, T. J., Nuzzo, R. G. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 1676-1678.

127.	"Thermal Decomposition of Di(Cycloalkyl)bis(triethylphosphine)platinum-(II) Complexes", Nuzzo, R. G., McCarthy, T. J. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 3404-3410.

126.	"Mechanisms of Thermal Decomposition of Diethylbis(triethylphosphine)-platinum(II)", McCarthy, T. J., Nuzzo, R. G. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 3396-3403.

125.	"Ring Strain in Bis(triethylphosphine)-3,3-dimethylplatinacyclobutane is Small", Moore, S. S., DiCosimo, R., Sowinski, A. F. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 948-949.

124.	"Preparation of Tertiary Phosphine-Olefin Complexes of Platinum(0): A Convenient Synthesis of Ethylenebis(triethylphosphine)platinum(0)", Nuzzo, R. G., McCarthy, T. J. and Whitesides, G. M., Inorg. Chem., 1981, 20, 1312-1314.

123.	"Practical Enzymatic Syntheses of Ribulose-1,5-diphosphate and Ribose-5-phosphate", Wong, C.-H., McCurry, S. D. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 7938-7939.

122.	"Synthesis of Nicotinamide Adenine Dinucleotide (NAD) from Adenosine Monophosphate (AMP)", Walt, D. R., Rios-Mercadillo, V. M., Aug�, J. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 7805-7806.

121.	"Enzyme-Catalyzed Organic Synthesis: NADH Regeneration Using Formate Dehydrogenase", Shaked, Z. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 7104-7105.

120.	"Enzyme Immobilization by Condensation Copolymerization into Cross-linked Polyacrylamide Gels", Pollak, A., Blumenfield, H., Wax, M., Baughn, R. L. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 6324-6336.

119.	"Organic Synthesis Using Cofactor-Requiring Enzymes", Whitesides, G. M., in Enzymes: The Interface between Technology and Economics, J. P. Danehy and B. Wolnak, Eds., Marcel Dekker, Inc., New York, 1980, 17-24.

118.	"The Mechanism of Thermal Decomposition of Dineopentylbis(triethyl-phosphine)platinum(II): Formation of Bis(triethylphosphine)-3,3-dimethylplatinacyclobutane", Foley, P., DiCosimo, R. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 6713-6725.

117.	"Rates of Thiol-Disulfide Interchange Reactions Involving Proteins, and Kinetic Measurements of Thiol pKa Values", Shaked, Z., Szajewski, R. P. and Whitesides, G. M., Biochemistry, 1980, 19, 4156-4166.

116.	"Trappings of Free Alkyl Radical Intermediates in the Reaction of Alkyl Bromides with Magnesium", Lawrence, L. M. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 2493-2494.

115.	"Reactions of Tetrakis(triphenylphosphine)platinum(0) and Ethylenebis(triphenylphosphine)platinum(0) with Strong Proton Acids", Foley, P. and Whitesides, G. M., Inorg. Chem., 1980, 19, 1402-1404.

114.	"The Mechanism of Formation of Grignard Reagents: Corrosion of Metallic Magnesium by Alkyl Halides in Ethers", Hill, C. L., Vander Sande, J. B. and Whitesides, G. M., J. Org. Chem., 1980, 45, 1020-1028.

113.	"Rate Constants and Equilibrium Constants for Thiol-Disulfide Interchange Reactions Involving Oxidized Gluthathione", Szajewski, R. P. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 2011-2026.

112.	"Reductive Cleavage of Carbon-Halogen Bonds by Tri-n-butyltin Hydride, Lithium 4,4'-Dimethylbenzophenone Ketyl, and Metallic Magnesium", Barber, J. J. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 239-243.

111.	"The Mechanism of Formation of Grignard Reagents: The Kinetics of Reaction of Substituted Aryl Bromides with Magnesium and with Tri-n-butyltin Hydride in Ethereal Solvents", Roberts, H. R., Rogers, H. R., Mitchell, H. L. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 231-238.

110.	"The Mechanism of Formation of Grignard Reagents: The Rate of Reaction of Cyclopentyl Bromide with Magnesium is Transport-Limited in Diethyl Ether", Rogers, H. R., Deutch, J. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 226-231.

109.	"The Mechanism of Formation of Grignard Reagents: The Kinetics of Reaction of Alkyl Halides in Diethyl Ether with Magnesium", Rogers, H. R., Hill, C. L., Fijiwara, Y., Rogers, R. J., Mitchell, H. L. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 217-226.

Publications 1980-1989