Whitesides Research

Whitesides Group Publications: The 1970s

108."Conversion of the Adenosine Moieties of RNA to ATP for Use in Cofactor Recycling", Leuchs, H.J., Lewis, J.M., Rios-Mercadillo, V.M., and Whitesides, G.M., J. Am. Chem. Soc., 1979, 101, 5829-5830. Download PDF

107."Large-Scale Enzymatic Synthesis of sn-Glycerol 3-Phosphate", Rios-Mercadillo, V.M., and Whitesides, G.M., J. Am. Chem. Soc., 1979, 101, 5828-5829. Download PDF

106."A Basis for Orbital Symmetry Rules", Metieu, H., Ross, J., and Whitesides, G.M., Angew. Chem. Int. Ed. Engl., 1979, 18, 377-392. Download PDF

105."Preparation and Magnetic Filtration of Polyacrylamide Gel Beads Containing a Ferrofluid and Covalently Immobilized Proteins", Adalsteinsson, O., Lamotte, A., Baddour, R.F., Colton, C.K., Pollak, A., and Whitesides, G.M., J. Mol. Cat., 1979, 6, 199-225. Download PDF

104."Polyacrylamide Gel Entrapment of Adenylate Kinase", Whitesides, G.M., Lamotte, A.L., Adalsteinsson, O., Baddour, R.F., Chmurny, A.C., and Colton, C.K., J. Mol. Cat., 1979, 6, 177-198. Download PDF

103."Conversion of CH2=CHR to CH2=CR'R by Reaction with Cp2TiCl2/AIR'3", Barber, J.J., Willis, C., and Whitesides, G.M., J. Org. Chem., 1979, 44, 3603-3606. Download PDF

102."Water-Soluble Complexes of tert-Phosphines and Rhodium(I) as Homogenous Catalysts", Nuzzo, R.G., Feitler, D., and Whitesides, G.M., J. Am. Chem. Soc., 1979, 101, 3683-3685. Download PDF

101."SN2 Displacement and Reductive Coupling of Ketones with Olefins in N,N-Diethylacetamide and N-Ethylpyrrolidone", Sowinski, A.F., and Whitesides, G.M., J. Org. Chem., 1979, 44, 2369-2376. Download PDF

100."Thermal Generation of Bis(triethylphosphine)-3,3-dimethylplatinacyclobutane from Dineopentylbis(triethylphosphine)platinum(II)", Foley, P., and Whitesides, G.M., J. Org. Chem., 1979, 101, 2732-2733. Download PDF

99."An Improved Synthesis of Diammonium Acetyl Phosphate", Lewis, J.M., Haynie, S.L., and Whitesides, G.M., J. Org. Chem., 1979, 44, 864-865. Download PDF

98."Hydrogenation of Oriented Monolayers of w-Unsaturated Fatty Acids Supported on Platinum", Richard, M.A., Deutch, J., and Whitesides, G.M., J. Am. Chem. Soc., 1978, 100, 6613-6625. Download PDF

97."Oxidative Addition and Reductive Elimination Reactions Involving Platinum Metallocycles", Young, G.B., and Whitesides, G.M., J. Am. Chem. Soc., 1978, 100, 5808-5815. Download PDF

96."Generalized Affinity Chromatography: Enzyme-Sulfonamide Conjugates Can Be Isolated by Adsorption on Immobilized Carbonic Anhydrase", Horowitz, R., and Whitesides, G.M., J. Am. Chem. Soc., 1978, 100, 4632-4633. Download PDF

95."Bis(2-diphenylphosphinoethyl)amine: A Flexible Synthesis of Functionalized Chelating Diphosphines", Wilson, M.E., Nuzzo, R.G., and Whitesides, G.M., J. Am. Chem. Soc., 1978, 100, 2269-2270. Download PDF

94."Conversion of a Protein to a Homogeneous Asymmetric Hydrogenation Catalyst by Site-Specific Modification with a Diphosphinerhodium(I) Moiety", Wilson, M.E., and Whitesides, G.M., J. Am. Chem. Soc., 1978, 100, 306-307. Download PDF

93."Large-Scale Enzyme-Catalyzed Synthesis of ATP from Adenosine and Acetyl Phosphate: Regeneration of ATP from AMP", Baughn, R.L., Adalsteinsson, O., and Whitesides, G.M., J. Am. Chem. Soc., 1978, 100, 304-306. Download PDF

92."Immobilization of Synthetically Useful Enzymes by Condensation Polymerization", Pollak, A., Baughn, R.L., Adalsteinsson, O., and Whitesides, G.M., J. Am. Chem. Soc., 1978, 100, 302-304. Download PDF

91."Large-Scale ATP-Requiring Enzymatic Phosphorylation of Creatine Can Be Driven by Enzymatic ATP Regeneration", Shih, Y.-S., and Whitesides, G.M., J. Org. Chem., 1977, 42, 4165-4166. Download PDF

90."The Stereochemistry of the Peters Reaction (RSO2HgX→RHgX)", Costa, L.C., and Whitesides, G.M., J. Organometal. Chem., 1977, 139, 151-163. Download PDF

89."The Location and Mobility of Functional Groups at the Surface of Oxidized, Low-Density Polyethylene Film", Rasmussen, J.R., Bergbreiter, D.E., and Whitesides, G.M., J. Am. Chem. Soc., 1977, 99, 4746-4756. Download PDF

88."Introduction, Modification, and Characterization of Functional Groups on the Surface of Low-Density Polyethylene Film", Rasmussen, J.R., Stedronsky, D.R., and M., G.W., J. Am. Chem. Soc., 1977, 99, 4736-4745. Download PDF

87."Vinylic Radicals are Intermediates in the Oxidation of Vinylic Lithium Reagents to Lithium Enolates by Dioxygen, but not by Lithium tert-Butyl peroxide", Panek, E.J., Kaiser, L.R., and Whitesides, G.M., J. Am. Chem. Soc., 1977, 99, 3708-3713. Download PDF

86."Propane-1,3-di(magnesium halide)", Costa, L.C., and Whitesides, G.M., J. Am. Chem. Soc., 1977, 99, 2390-2391. Download PDF

85."Large-Scale Enzymatic Synthesis with Cofactor Regeneration: Glucose-6-Phosphate", Pollak, A., Baughn, R.L., and Whitesides, G.M., J. Am. Chem. Soc., 1977, 99, 2366-2367. Download PDF

84."Rates of Thiol-Disulfide Interchange Reactions between Mono- and Dithiols and Ellman's Reagent", Whitesides, G.M., Lilburn, J.E., and Szajewski, R.P., J. Org. Chem., 1977, 42, 332-338. Download PDF

83."Covalent Immobilization of Adenylate Kinase and Acetate Kinase in Polyacrylamide Gels: Enzymes for ATP Regeneration", Whitesides, G.M., Lamotte, A., Adalsteinsson, O., and Colton, C.L., Methods in Enzymology, Mosbach, K., Eds., Academic Press, 1976, XLIV: Immobilized Enzymes. Download PDF

82."Affinity Chromatography", Whitesides, G.M., and Nishikawa, A.H., Applications of Biochemical Systems in Organic Chemistry, Part 2, Jones, J.B., Perlman, D., and Sih, C.J., Eds., John Wiley & Sons, 1976. Download PDF

81."Large-Scale Organic Synthesis Using Cell-Free Enzymes", Whitesides, G.M., Applications of Biochemical Systems in Organic Chemistry, Part 2, Jones, J.B., Perlman, D., and Sih, C.J., Eds., John Wiley & Sons, 1976. Download PDF

80."Synthesis and Reactions of Dicyclopentadienyltitanium(IV) Metallocycles", McDermott, J.X., Wilson, M.E., and Whitesides, G.M., J. Am. Chem. Soc., 1976, 98, 6529-6536. Download PDF

79."Thermal Decomposition of Bis(phosphine)platinum(II) Metallocycles", McDermott, J.X., White, J.F., and Whitesides, G.M., J. Am. Chem. Soc., 1976, 98, 6521-6528. Download PDF

78."High-Gradient Magnetic Filtration of Small Particles of Ferro-, Ferri-, and Paramagnetic Catalysts and Catalyst Supports", Hill, C.L., Lamotte, A., Althoff, W., Brunie, J.C., and Whitesides, G.M., J. Cat., 1976, 43, 53-60. Download PDF

77."Convenient Preparations of a 1,2,3,4,5-Pentamethylcyclopentadiene and 1-Ethyl-2,3,4,5-Tetramethylcyclopentadiene", Feitler, D., and Whitesides, G.M., Inorg. Chem., 1976, 15, 446-449. Download PDF

76."Organic Synthesis Using Enzymes in Two-Phase Aqueous Polymer Systems", Pollak, A., and Whitesides, G.M., J. Am. Chem. Soc., 1976, 98, 289-291. Download PDF

75."Reaction of a,w-diGrignard Reagents with Silver(I) Salts Forms Carbocyclic Rings", Whitesides, G.M., and Gutowski, F.D., J. Org. Chem., 1976, 41, 2882-2885. Download PDF

74."Magnetic Filtration of Small Heterogenous Catalyst Particles: Preparation of Ferrimagnetic Catalyst Supports", Whitesides, G.M., Hill, C.L., and Brunie, J.C.I.&.E., Process Res. Devel., 1976, 15, 226-227. Download PDF

73."Olefins by Reaction of Lithium Dipropenylcuprates with Alkyl Halides: trans-2-Undecene", Linstrumelle, G., Krieger, J.K., and Whitesides, G.M., Org. Syn., 1976, 55, 103-106.

72."The Oxidation of Terminal Olefins to Methyl Ketones by Jones' Reagent is Catalyzed by Mercury(II)", Rogers, H.R., McDermott, J.X., and Whitesides, G.M., J. Org. Chem., 1975, 40, 3577-3580. Download PDF

71."The Reaction of n-Butyllithium and 2,2,6,6-Tetramethylpiperdine Nitroxyl", Whitesides, G.M., and Newirth, T.L., J. Org. Chem., 1975, 40, 3448-3450. Download PDF

70."A Dynamic NMR Study of Fluorine Exchange in Liquid SF4", Klemperer, W.G., Krieger, J.K., McCreary, M.D., Muetterties, E.L., Traficante, D.D., and Whitesides, G.M., J. Am. Chem. Soc., 1975, 97, 7023-7030. Download PDF

69."Large-Scale Synthesis of Diammonium Acetyl Phosphate", Whitesides, G.M., Siegel, M., and Garrett, P., J. Org. Chem., 1975, 40, 2516-2519. Download PDF

68."Mechanisms of Thermal Decomposition of Transition Metal Organometallic Compounds", Whitesides, G.M., Organotransition-Metal Chemistry, Ishii, Y., and Tsutsui, M., Eds., Plenum Press, 1975.

67."The Synthesis of Fatty Acids Using Organocopper(I) Ate Complexes Derived from Grignard Reagents", Bergbreiter, D.E., and Whitesides, G.M., J. Org. Chem., 1975, 40, 779-782. Download PDF

66."Generation and Utilization of Copper(I) Ate Complexes from Diastereomeric and Enantiomeric Alkylmercury Reagents", Bergbreiter, D.E., and Whitesides, G.M., J. Am. Chem. Soc., 1974, 96, 4937-4944.. Download PDF

65."Pseudorotation in Arylbis(4,4'-dimethyl-2,2'-biphenylylene)phosphoranes", Whitesides, G.M., Eisenhut, M., and Bunting, W.M., J. Am. Chem. Soc., 1974, 96, 5398-5407. Download PDF

64."Pseudorotation in XPF4", Eisenhut, M., Mitchell, H.L., Traficante, D.D., Kaufman, R.J., Deutch, J.M., and Whitesides, G.M., J. Am. Chem. Soc., 1974, 96, 5385-5397. Download PDF

63."Copper(I) Alkoxides: Synthesis, Reactions, and Thermal Decomposition", Whitesides, G.M., Sadowski, J.S., and Lilburn, J., J. Am. Chem. Soc., 1974, 96, 2829-2835. Download PDF

62."Preparation and Reactions of a Titanium(IV) Metallocycle Formation of Cyclopentanone from Ethylene and Carbon Monoxide", McDermott, J.X., and Whitesides, G.M., J. Am. Chem. Soc., 1974, 96, 947-948. Download PDF

61."Enzymatic Regeneration of ATP from AMP and ADP. Part II: Enzyme Immobilization and Reactor Development", Whitesides, G.M., Chmurny, A., Garrett, P., Lamotte, A., and Colton, C.K., Enzyme Engineering, Pye, K.E., and Wingard, L.B., Eds., Plenum Press, 1974, 2. Download PDF

60."Enzymatic Regeneration of ATP from AMP and ADP. Part I: Thermodynamics, Kinetics, and Process Development", Gardner, C.R., Colton, C.K., Langer, R.S., Hamilton, B.K., Archer, M.C., and Whitesides, G.M., Enzyme Engineering, Pye, K.E., and Wingard, L.B., Eds., Plenum Press, 1974, 2. Download PDF

59."Kinetics of Formation of Alkyl Grignard Reagents: Evidence for Rate-Determining Electron Transfer", Rogers, R.J., Mitchell, H.L., and Whitesides, G.M., J. Org. Chem., 1974, 39, 857-858. Download PDF

58."The Stereoselective Synthesis of 1-Substituted Organometallic Derivatives of 3,3-Dimethylbutane-1,2-d2", Bock, P.L., and Whitesides, G.M., J. Am. Chem. Soc., 1974, 96, 2826-2829. Download PDF

57."The Stereochemistry of Reactions at Carbon-Transition Metal s-Bonds. (CH3)3CCHDCHDFe(CO)2C5H5", Bock, P.L., Boschetto, D.J., Rasmussen, J.R., Demers, J.P., and Whitesides, G.M., J. Am. Chem. Soc., 1974, 96, 2814-2825. Download PDF

56."The Preparation and Thermal Decomposition of n-Alkyl(tri-n-butyl-phosphine)silver(I) Reagents", Whitesides, G.M., Bergbreiter, D., and Kendall, P.E., J. Am. Chem. Soc., 1974, 96, 2806-2813. Download PDF

55."The Determination of Enantiomeric Purity Using Chiral Lanthanide Shift Reagents", McCreary, M.D., Lewis, D.W., Wernick, D.L., and Whitesides, G.M., J. Am. Chem. Soc., 1974, 96, 1038-1054. Download PDF

54."Reactions of Alkylmercuric Halides with Sodium Borohydride in the Presence of Molecular Oxygen", Hill, C.L., and Whitesides, G.M., J. Am. Chem. Soc., 1974, 96, 870-876. Download PDF

53."Selectivity in Organic Group Transfer in Reactions and Mixed Lithium Diorganocuprates", Mandeville, W.H., and Whitesides, G.M., J. Org. Chem., 1974, 39, 400-405. Download PDF

52."The Mechanism of Reaction of Carbon Monoxide with Phenyllithium", Trzupek, L.S., Newirth, T.L., Kelly, E.G., Sbarbati, N.E., and Whitesides, G.M., J. Am. Chem. Soc., 1973, 95, 8118-8133. Download PDF

51."Inversion of Configuration in the Bromination of Vinylic Mercurials", Casey, C.P., Whitesides, G.M., and Kurth, J., J. Org. Chem., 1973, 38, 3406-3410. Download PDF

50."The Preparation and Thermal Decomposition of Platinum(II) Metallocycles", McDermott, J.X., White, J.F., and Whitesides, G.M., J. Am. Chem. Soc., 1973, 95, 4451-4452. Download PDF

49."Reactions of Transition Metal Peroxides with n-Butyllithium", Regen, S.L., and Whitesides, G.M., J. Organometal. Chem., 1973, 59, 293-297. Download PDF

48."The Mechanism of Interchange of the Syn and Anti protons of Tetra(trihaptoallyl)zirconium(IV)", Krieger, J.K., Deutch, J.M., and Whitesides, G.M., Inorg. Chem., 1973, 12, 1535-1545.. Download PDF

47."ESR Study of the Radical Ions of 1,2,3,4-Tetramethylnapthalene", Gerson, F., Peake, B.M., and Whitesides, G.M., Org. Mag. Res., 1972, 4, 361-363. Download PDF

46."Free Radical Intermediates in the Reaction of Neophyllithium with Oxygen", Panek, E.J., and Whitesides, G.M., J. Am. Chem. Soc., 1972, 94, 8768-8675. Download PDF

45."The Stereochemistry of the Conjugate Addition of Derivatives of endo-2-Norbornylcopper(I) to Mesityl Oxide", Whitesides, G.M., and Kendall, P.E., J. Org. Chem., 1972, 37, 3718-3725. Download PDF

44."Preparation of Deuterated Organic Compounds from Activated Organic Halides by Reduction with Zinc", Trzupek, L.S., Stedronsky, E.R., and Whitesides, G.M., J. Org. Chem., 1972, 37, 3300-3303. Download PDF

43."Nitrogen and Boron Spin-Lattice Relaxation in Borazole", Whitesides, G.M., Regen, S.L., Lisle, J.B., and Mays, R., J. Phys. Chem., 1972, 76, 2871-2877.. Download PDF

42."Mechanism of Thermal Decomposition of Di-n-butylbis(triphenyl-phosphine)platinum(II)", Whitesides, G.M., Gaasch, J.F., and Stedronsky, E.R., J. Am. Chem. Soc., 1972, 94, 5258-5270. Download PDF

41."The Catalytic Oxidation of Vicinal Diols to a-Diketones", Regen, S.L., and Whitesides, G.M., J. Org. Chem., 1972, 37, 1832-1833. Download PDF

40."Radical Intermediates in the Thermal Decomposition of Neophyl(tri-n-butylphosphine)silver(I)", Whitesides, G.M., Panek, E.J., and Stedronsky, E.R., J. Am. Chem. Soc., 1972, 94, 232-240. Download PDF

39."The Determination of Enantiomeric Purity Using Chiral Lanthanide Shift Reagents", Whitesides, G.M., and Lewis, D.W., J. Am. Chem. Soc., 1971, 93, 5914-5916. Download PDF

38."Analysis of the 1H NMR Spectrum of Di-n-butyl-2,2-d2 bis(triphenylphos-phine)platinum(II)", Whitesides, G.M., and Gaasch, J.F., J. Organometal.Chem., 1971, 33, 241-246. Download PDF

37."The Stereochemistry of Reactions Occurring at Iron-carbon s-Bonds", Whitesides, G.M., and Boschetto, D.J., J. Am. Chem. Soc., 1971, 93, 1529-1531. Download PDF

36."The Thermal Decomposition of Vinylic Copper(I) and Silver(I) Organometallic Compounds", Whitesides, G.M., Casey, C.P., and Krieger, J.K., J. Am. Chem. Soc., 1971, 93, 1379-1389. Download PDF

35a."Reduction of Olefins Using Sodium-Hexamethylphosphoramide-t-Butyl Alcohol1", Whitesides, G.M., and Ehmann, W.J., Journal of Organic Chemistry , 1970, 35, 3565-3567. Download PDF

35."Tris[3-(t-butylhydroxymethylene)-d-camphorato]europium(III): a Reagent for Determining Enantiomeric Purity", Whitesides, G.M., and Lewis, D.W., J. Am. Chem. Soc., 1970, 92, 6979-6980. Download PDF

34."The Mechanism of Reduction of Alkylmercuric Halides by Metal Hydrides", Whitesides, G.M., and San Filippo, J., Jr., J. Am. Chem. Soc., 1970, 92, 6611-6624. Download PDF

33."The Mechanism of Formation of 1,2,3,4-Tetramethylnapthalene from 2-Butyne and Triphenyltris(tetrahydrofuran)chromium(III)", Whitesides, G.M., and Ehmann, W.J., J. Am. Chem. Soc., 1970, 92, 5625-5640. Download PDF

32."(p→d)p Bonding in Phenyltrichloro-tin, -germane, and -silane", Whitesides, G.M., Selgestad, J.G., Thomas, S.P., Andrews, D.W., Morrison, B.A., Panek, E.J., and San Filippo, J., Jr., J. Organometal. Chem., 1970, 22, 365-374. Download PDF

31."The Mechanism of Thermal Decomposition of n-Butyl(tri-n-butylphosphine)copper(I)", Whitesides, G.M., Stedronsky, E.R., Casey, C.P., and San Filippo, J., Jr., J. Am. Chem. Soc., 1970, 92, 1426-1427. Download PDF

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