Grignard Reactions and RLi Chemistry

1989
K. S. Root, C. L. Hill, L. M. Lawrence, and G. M. Whitesides. 1989. “The Mechanism of Formation of Grignard Reagents: Trapping of Free Alkyl Radical Intermediates by Reaction with Tetramethylpiperidine-N-oxyl.” J. Am. Chem. Soc., 111, Pp. 5405-5412. PDF
261
1988
M. R. Callstrom, T.X. Neenan, and G. M. Whitesides. 1988. “Poly(3-n-butyl-2,5-diethynylenethiophenylene): A Soluble Polymer Containing Diacetylene Units and Its Conversion to a Highly-Cross-Linked Organic Solid.” Macromolecules, 21, Pp. 3528-3530. PDF
241
1986
J.F. Garst, J. Deutch, and G. M. Whitesides. 1986. “Radical Isomerization during Grignard Reagent Formation. A Quantitative Treatment.” J. Am. Chem. Soc., 108, Pp. 2490-2491. PDF
191
1983
G. M. Whitesides. 1983. “Relations between Fracture and Coordination Chemistry.” In Atomistics of Fracture, edited by R.M. Latanision and J.R. Pickens, Pp. 337-362. New York: Plenum Press. PDF
155
1982
S.S. Moore and G. M. Whitesides. 1982. “Synthesis and Coordinating Properties of Heterocyclic Tertiary Phosphines.” J. Org. Chem., 47, Pp. 1489-1493. PDF
145
1981
K. S. Root, J. Deutch, and G. M. Whitesides. 1981. “The Mechanism of Formation of Grignard Reagents. The Rate of Reaction of Cyclopentyl Bromide with a Rotating Magnesium Disk.” J. Am. Chem. Soc., 103, Pp. 5475-5479. PDF
132
1980
C. L. Hill, J. B. Vander Sande, and G. M. Whitesides. 1980. “The Mechanism of Formation of Grignard Reagents: Corrosion of Metallic Magnesium by Alkyl Halides in Ethers.” J. Org. Chem., 45, Pp. 1020-1028. PDF
114
H. R. Roberts, H.R. Rogers, H.L. Mitchell, and G. M. Whitesides. 1980. “The Mechanism of Formation of Grignard Reagents: The Kinetics of Reaction of Substituted Aryl Bromides with Magnesium and with Tri-n-butyltin Hydride in Ethereal Solvents.” J. Am. Chem. Soc., 102, Pp. 231-238. PDF
111
H.R. Rogers, C. L. Hill, Y. Fijiwara, R. J. Rogers, H.L. Mitchell, and G. M. Whitesides. 1980. “The Mechanism of Formation of Grignard Reagents: The Kinetics of Reaction of Alkyl Halides in Diethyl Ether with Magnesium.” J. Am. Chem. Soc., 102, Pp. 217-226. PDF
109
H.R. Rogers, J. Deutch, and G. M. Whitesides. 1980. “The Mechanism of Formation of Grignard Reagents: The Rate of Reaction of Cyclopentyl Bromide with Magnesium is Transport-Limited in Diethyl Ether.” J. Am. Chem. Soc., 102, Pp. 226-231. PDF
110
J.J. Barber and G. M. Whitesides. 1980. “Reductive Cleavage of Carbon-Halogen Bonds by Tri-n-butyltin Hydride, Lithium 4,4'-Dimethylbenzophenone Ketyl, and Metallic Magnesium.” J. Am. Chem. Soc., 102, Pp. 239-243. PDF
112
L. M. Lawrence and G. M. Whitesides. 1980. “Trappings of Free Alkyl Radical Intermediates in the Reaction of Alkyl Bromides with Magnesium.” J. Am. Chem. Soc., 102, Pp. 2493-2494. PDF
116
1979
A.F. Sowinski and G. M. Whitesides. 1979. “SN2 Displacement and Reductive Coupling of Ketones with Olefins in N,N-Diethylacetamide and N-Ethylpyrrolidone.” J. Org. Chem., 44, Pp. 2369-2376. PDF
101
1978
M.E. Wilson, R.G. Nuzzo, and G. M. Whitesides. 1978. “Bis(2-diphenylphosphinoethyl)amine: A Flexible Synthesis of Functionalized Chelating Diphosphines.” J. Am. Chem. Soc., 100, Pp. 2269-2270. PDF
95
1977
L.C. Costa and G. M. Whitesides. 1977. “Propane-1,3-di(magnesium halide).” J. Am. Chem. Soc., 99, Pp. 2390-2391. PDF
86
L.C. Costa and G. M. Whitesides. 1977. “The Stereochemistry of the Peters Reaction (RSO2HgXàRHgX).” J. Organometal. Chem., 139, Pp. 151-163. PDF
90
E.J. Panek, L.R. Kaiser, and G. M. Whitesides. 1977. “Vinylic Radicals are Intermediates in the Oxidation of Vinylic Lithium Reagents to Lithium Enolates by Dioxygen, but not by Lithium tert-Butyl peroxide.” J. Am. Chem. Soc., 99, Pp. 3708-3713. PDF
87
1976
D. Feitler and G. M. Whitesides. 1976. “Convenient Preparations of a 1,2,3,4,5-Pentamethylcyclopentadiene and 1-Ethyl-2,3,4,5-Tetramethylcyclopentadiene.” Inorg. Chem., 15, Pp. 446-449. PDF
77
G. Linstrumelle, J.K. Krieger, and G. M. Whitesides. 1976. “Olefins by Reaction of Lithium Dipropenylcuprates with Alkyl Halides: trans-2-Undecene.” Org. Syn., 55, Pp. 103-106.
73
G. M. Whitesides and F.D. Gutowski. 1976. “Reaction of a,w-diGrignard Reagents with Silver(I) Salts Forms Carbocyclic Rings.” J. Org. Chem., 41, Pp. 2882-2885. PDF
75

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