PHYSICAL ORGANIC SCIENCE

1986
M. Hackett, J.A. Ibers, P. Jernakoff, and G. M. Whitesides. 1986. “Cis[bis(dicyclohexylphosphino)ethane]platinum(0) Reacts with Unactivated Carbon-Hydrogen Bonds.” J. Am. Chem. Soc., 108, Pp. 8094-8095. PDF
194
T.M. Miller and G. M. Whitesides. 1986. “The Mechanism of Thermal Decomposition of Bis(tricyclopentylphosphine)-platinacyclopentane(II): Intramolecular b-Hydride Elimination from the Platinacyclopentane Ring is Slow Relative to an Intermolecular Chain Reaction Involving Hydridoplatinum I.” Organometallics, 5, Pp. 1473-1480. PDF
186
R.L. Brainard, T.M. Miller, and G. M. Whitesides. 1986. “The Mechanisms of Thermal Decomposition of trans-Chloroneopentylbis(tricyclopentylphosphine)platinum(II).” Organometallics, 5, Pp. 1481-1490. PDF
188
J.F. Garst, J. Deutch, and G. M. Whitesides. 1986. “Radical Isomerization during Grignard Reagent Formation. A Quantitative Treatment.” J. Am. Chem. Soc., 108, Pp. 2490-2491. PDF
191
W.H. Mandeville and G. M. Whitesides. 1986. “Synthesis of a Water-Soluble Derivative of Cyclohexatriacontane-1,2,13,14,25,26-hexone.” J. Org. Chem., 51, Pp. 3257-3261. PDF
192
1985
R.L. Brainard and G. M. Whitesides. 1985. “The Mechanism of Thermal Decomposition of trans-Chloroethylbis-(triethylphosphine)platinum(II).” Organometallics, 4, Pp. 1550-1557. PDF
178
G. M. Whitesides, M. Hackett, R.L. Brainard, J-P.P.M. Lavalleye, A.F. Sowinski, A.N. Izumi, S.S. Moore, D.W. Brown, and E.M. Staudt. 1985. “Suppression of Unwanted Heterogeneous Platinum(0)-Catalyzed Reactions by Poisoning with Mercury(0) in Systems Involving Competing Homogeneous Reactions of Soluble Organoplatinum Compounds: Thermal Decomposition of Bis(triethylphosphine)-3,3,4,4-tet.” Organometallics, 4, Pp. 1819-1830. PDF
179
1984
R.H. Reamey and G. M. Whitesides. 1984. “The Mechanism of Hydrogenolysis of Dineopentylbis(triethylphosphine)platinum(II).” J. Am. Chem. Soc., 106, Pp. 81-85. PDF
167
1983
G. M. Whitesides, R.H. Reamey, R.L. Brainard, A.N. Izumi, and T.J. McCarthy. 1983. “Organometallic Reactions of Platinum Involving Metallic Hydrides.” Annals New York Acad. Sci., 415, Pp. 56-66. PDF
166
G. M. Whitesides. 1983. “Relations between Fracture and Coordination Chemistry.” In Atomistics of Fracture, edited by R.M. Latanision and J.R. Pickens, Pp. 337-362. New York: Plenum Press. PDF
155
1982
B.L. Hirschbein and G. M. Whitesides. 1982. “Affinity Separation of Enzymes from Mixtures Containing Suspended Solids: Comparisons of Magnetic and Non-Magnetic Techniques.” Appl. Biochem. Biotech., 7, Pp. 157-176. PDF
141
R. DiCosimo, S.S. Moore, A.F. Sowinski, and G. M. Whitesides. 1982. “Cyclometalation of Dialkylbis(triethylphosphine)platinum(II) Complexes: Formation of Pt, Pt-Bis(triethylphosphine)platinacycloalkanes.” J. Am. Chem. Soc., 104, Pp. 124-133. PDF
139
B.L. Hirschbein, D.W. Brown, and G. M. Whitesides. 1982. “Magnetic Separations in Chemistry and Biochemistry.” Chemtech., 12, Pp. 172-179. PDF
144
R. DiCosimo and G. M. Whitesides. 1982. “Reductive Elimination of a Carbon-Carbon Bond from Bis(trialkylphosphine)-3,3-dimethylplatinacyclopropane Produces Bis(trialkylphosphine)-platinum(0) and 1,1-Dimethylcyclopropane.” J. Am. Chem. Soc., 104, Pp. 3601-3607. PDF
146
A. C. Balazs, K. H. Johnson, and G. M. Whitesides. 1982. “Reductive Elimination of H-H, H-CH3, and CH3-CH3 from Bis(phosphine)-platinum(II), -palladium(II), and -nickel(II) Complexes: A Theoretical Study Using the SCF-Xa-SW Method.” Inorg. Chem., 21, Pp. 2162-2174. PDF
143
J.C. Ibers, R. DiCosimo, and G. M. Whitesides. 1982. “Structures of Dineopentylbis(triethylphosphine)platinum(II) and Bis(triethylphosphine)-3,3-dimethylplatinacyclobutane: Reactant and Product in a Thermal Cyclometallation Reaction.” Organometallics, 1, Pp. 13-20. PDF
142
S.S. Moore and G. M. Whitesides. 1982. “Synthesis and Coordinating Properties of Heterocyclic Tertiary Phosphines.” J. Org. Chem., 47, Pp. 1489-1493. PDF
145
1981
T.J. McCarthy, R.G. Nuzzo, and G. M. Whitesides. 1981. “Apparent Fluxionality in Diethyl(phosphine)platinum(II), a Coordinately Unsaturated Intermediate in b-Hydride Elimination.” J. Am. Chem. Soc., 103, Pp. 1676-1678. PDF
128
T.J. McCarthy, Y-S. Shih, and G. M. Whitesides. 1981. “Heterogenous Platinum-Catalyzed Hydrogenation of Dialkyl(diolefin)platinum(II) Complexes.” Proc. Nat. Acad. Sci. USA, 78, Pp. 4649-4651. PDF
131
K. S. Root, J. Deutch, and G. M. Whitesides. 1981. “The Mechanism of Formation of Grignard Reagents. The Rate of Reaction of Cyclopentyl Bromide with a Rotating Magnesium Disk.” J. Am. Chem. Soc., 103, Pp. 5475-5479. PDF
132

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