Mechanism of Formation of RMgX

1989
K. S. Root, C. L. Hill, L. M. Lawrence, and G. M. Whitesides. 1989. “The Mechanism of Formation of Grignard Reagents: Trapping of Free Alkyl Radical Intermediates by Reaction with Tetramethylpiperidine-N-oxyl.” J. Am. Chem. Soc., 111, Pp. 5405-5412. PDF
261
1986
J.F. Garst, J. Deutch, and G. M. Whitesides. 1986. “Radical Isomerization during Grignard Reagent Formation. A Quantitative Treatment.” J. Am. Chem. Soc., 108, Pp. 2490-2491. PDF
191
1980
C. L. Hill, J. B. Vander Sande, and G. M. Whitesides. 1980. “The Mechanism of Formation of Grignard Reagents: Corrosion of Metallic Magnesium by Alkyl Halides in Ethers.” J. Org. Chem., 45, Pp. 1020-1028. PDF
114