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PHYSICAL ORGANIC SCIENCE
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ORGANOMETALLIC CHEMISTRY
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Grignard Reactions and RLi Chemistry
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1989
K. S. Root, C. L. Hill, L. M. Lawrence, and G. M. Whitesides
. 1989. “
The Mechanism of Formation of Grignard Reagents: Trapping of Free Alkyl Radical Intermediates by Reaction with Tetramethylpiperidine-N-oxyl
.” J. Am. Chem. Soc., 111, Pp. 5405-5412.
PDF
261
1988
M. R. Callstrom, T.X. Neenan, and G. M. Whitesides
. 1988. “
Poly(3-n-butyl-2,5-diethynylenethiophenylene): A Soluble Polymer Containing Diacetylene Units and Its Conversion to a Highly-Cross-Linked Organic Solid
.” Macromolecules, 21, Pp. 3528-3530.
PDF
241
1986
J.F. Garst, J. Deutch, and G. M. Whitesides
. 1986. “
Radical Isomerization during Grignard Reagent Formation. A Quantitative Treatment
.” J. Am. Chem. Soc., 108, Pp. 2490-2491.
PDF
191
1983
G. M. Whitesides
. 1983. “
Relations between Fracture and Coordination Chemistry
.” In Atomistics of Fracture,
edited by R.M. Latanision and J.R. Pickens
, Pp. 337-362. New York: Plenum Press.
PDF
155
1982
S.S. Moore and G. M. Whitesides
. 1982. “
Synthesis and Coordinating Properties of Heterocyclic Tertiary Phosphines
.” J. Org. Chem., 47, Pp. 1489-1493.
PDF
145
1981
K. S. Root, J. Deutch, and G. M. Whitesides
. 1981. “
The Mechanism of Formation of Grignard Reagents. The Rate of Reaction of Cyclopentyl Bromide with a Rotating Magnesium Disk
.” J. Am. Chem. Soc., 103, Pp. 5475-5479.
PDF
132
1980
C. L. Hill, J. B. Vander Sande, and G. M. Whitesides
. 1980. “
The Mechanism of Formation of Grignard Reagents: Corrosion of Metallic Magnesium by Alkyl Halides in Ethers
.” J. Org. Chem., 45, Pp. 1020-1028.
PDF
114
H. R. Roberts, H.R. Rogers, H.L. Mitchell, and G. M. Whitesides
. 1980. “
The Mechanism of Formation of Grignard Reagents: The Kinetics of Reaction of Substituted Aryl Bromides with Magnesium and with Tri-n-butyltin Hydride in Ethereal Solvents
.” J. Am. Chem. Soc., 102, Pp. 231-238.
PDF
111
H.R. Rogers, C. L. Hill, Y. Fijiwara, R. J. Rogers, H.L. Mitchell, and G. M. Whitesides
. 1980. “
The Mechanism of Formation of Grignard Reagents: The Kinetics of Reaction of Alkyl Halides in Diethyl Ether with Magnesium
.” J. Am. Chem. Soc., 102, Pp. 217-226.
PDF
109
H.R. Rogers, J. Deutch, and G. M. Whitesides
. 1980. “
The Mechanism of Formation of Grignard Reagents: The Rate of Reaction of Cyclopentyl Bromide with Magnesium is Transport-Limited in Diethyl Ether
.” J. Am. Chem. Soc., 102, Pp. 226-231.
PDF
110
J.J. Barber and G. M. Whitesides
. 1980. “
Reductive Cleavage of Carbon-Halogen Bonds by Tri-n-butyltin Hydride, Lithium 4,4'-Dimethylbenzophenone Ketyl, and Metallic Magnesium
.” J. Am. Chem. Soc., 102, Pp. 239-243.
PDF
112
L. M. Lawrence and G. M. Whitesides
. 1980. “
Trappings of Free Alkyl Radical Intermediates in the Reaction of Alkyl Bromides with Magnesium
.” J. Am. Chem. Soc., 102, Pp. 2493-2494.
PDF
116
1979
A.F. Sowinski and G. M. Whitesides
. 1979. “
S
N
2 Displacement and Reductive Coupling of Ketones with Olefins in N,N-Diethylacetamide and N-Ethylpyrrolidone
.” J. Org. Chem., 44, Pp. 2369-2376.
PDF
101
1978
M.E. Wilson, R.G. Nuzzo, and G. M. Whitesides
. 1978. “
Bis(2-diphenylphosphinoethyl)amine: A Flexible Synthesis of Functionalized Chelating Diphosphines
.” J. Am. Chem. Soc., 100, Pp. 2269-2270.
PDF
95
1977
L.C. Costa and G. M. Whitesides
. 1977. “
Propane-1,3-di(magnesium halide)
.” J. Am. Chem. Soc., 99, Pp. 2390-2391.
PDF
86
L.C. Costa and G. M. Whitesides
. 1977. “
The Stereochemistry of the Peters Reaction (RSO
2
HgXàRHgX)
.” J. Organometal. Chem., 139, Pp. 151-163.
PDF
90
E.J. Panek, L.R. Kaiser, and G. M. Whitesides
. 1977. “
Vinylic Radicals are Intermediates in the Oxidation of Vinylic Lithium Reagents to Lithium Enolates by Dioxygen, but not by Lithium tert-Butyl peroxide
.” J. Am. Chem. Soc., 99, Pp. 3708-3713.
PDF
87
1976
D. Feitler and G. M. Whitesides
. 1976. “
Convenient Preparations of a 1,2,3,4,5-Pentamethylcyclopentadiene and 1-Ethyl-2,3,4,5-Tetramethylcyclopentadiene
.” Inorg. Chem., 15, Pp. 446-449.
PDF
77
G. Linstrumelle, J.K. Krieger, and G. M. Whitesides
. 1976. “
Olefins by Reaction of Lithium Dipropenylcuprates with Alkyl Halides: trans-2-Undecene
.” Org. Syn., 55, Pp. 103-106.
73
G. M. Whitesides and F.D. Gutowski
. 1976. “
Reaction of a,w-diGrignard Reagents with Silver(I) Salts Forms Carbocyclic Rings
.” J. Org. Chem., 41, Pp. 2882-2885.
PDF
75
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